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Beilstein J. Org. Chem. 2016, 12, 1314–1321, doi:10.3762/bjoc.12.124
Graphical Abstract
Scheme 1: Syntheses to Cu(I) complex bearing a NHC ligand.
Scheme 2: Synthesis of Cu(II) terpyridyl complexes.
Scheme 3: Anchoring and refolding of the biohybrid copper complexes.
Figure 1: CD spectra of refolded catalysts 17–19 (red: 17, black: 18, blue: 19).
Figure 2: Temperature-dependent CD spectra of catalyst 17.
Figure 3: MALDI–TOF mass spectra (black: 17, red: FhuAΔCVFtev).